Optimized cleaning chain for the plasma coating of tools

Plasma fine-cleaning with pulsed plasma at differing plasma power.
© Fraunhofer IST, Sebastian Klemm
Plasma fine-cleaning with pulsed plasma at differing plasma power.

During the production of cutting tools, state of the surface and edge-layer arise which require the most efficient cleaning procedure possible in order to allow the subsequent coating. With the aim to avoid the use of suitably aggressive wet-chemical cleaning agents and simultaneously create further technological advantages, the Fraunhofer IST successfully participated in a DBU joint project, together with partners from industry and research, in which an alternative cleaning process chain was developed and evaluated.

Ziele für nachhaltige Entwicklung der Vereinten Nationen 6, 12 und 11: Sauberes Wasser und Sanitäreinrichtungen, verantwortungsvolle Konsum- und Produktionsmuster  und nachhaltige Städte und Gemeinden
Process chain in the project ‘ÖkoClean’, schematically.
© Falko Oldenburg
Process chain in the project ‘ÖkoClean’, schematically.
Plasma fine-cleaning with pulsed plasma at differing plasma power.
© Fraunhofer IST, Sebastian Klemm
Plasma fine-cleaning with pulsed plasma at differing plasma power.

The cleaning process chain

The developed combinations of balanced pretreatment processes enable a high cleaning effect with significantly reduced environmental pollution. Simultaneously, additional technological functions, such as the adjustment of the cutting-edge geometry for geometrically complex cutting tools, are possible. This results in an economical alternative to conventional cleaning processes.

In order to increase the process reliability of the subsequent vacuum coating processes during production, the following individual process steps were examined in different combinations and evaluated by investigating the wear behavior of coated tools in machining tests:

  • Aqueous two-stage cleaning procedure with biodegradable cleaning agents
  • CO2 dry-snow blasting for local residue-free cleaning
  • Plasma-electrolytical polishing with environmentally friendly media
  • Plasma fine-cleaning in vacuum with novel generator concepts

The individual processes

As a further development of the state-of-the-art in production, a two-stage cleaning concept was selected for the aqueous cleaning process in such a way that the greatest possible effect can be achieved with the smallest possible application quantity. The intelligent combination of active ingredients is biodegradable and retains the pH values of the utilized aqueous cleaning agents within a moderate neutral range.

Working with the CO2 snow jet, which is accelerated to supersonic speed, enables the efficient and gentle removal of particulate and film contamination such as dust, residues of polishing pastes, oils or cutting emulsions. This process can be automated and locally focussed for the cleaning of geometric areas which are difficult to access.

With plasma-electrolytical polishing (PEP), the component to be treated is cleaned and polished in an electrolyte of non-toxic salts and water by applying a voltage of several 100 V. In addition to very good cleaning results, burrs and impurities are removed in the same process step. Furthermore, the cutting-edge radii of the tools can be specifically adjusted.

For the final step of the pretreatment, the substrate surface at nanometer scale is cleaned from any chemical compounds under vacuum conditions by means of plasma-chemical and plasma-physical processes and chemically activated. This plays an important role, in particular as regards the bonding or adhesion of subsequently applied layers. Decisive for effective cleaning are the prevailing plasma conditions, which can be modified in wide ranges by varying the pulse geometry, acceleration voltages and plasma power (see Figure above).

Comparison of the individual cleaning processes

In the development of the process chain, various individual process combinations were applied to artificially contaminated cutting tools. In order to create the best-possible comparability, a synthetic reference contamination consisting of oils, fats, particles and suspensions used in the reference production chain was developed. Prior to the evaluation, the tools were qualified with regard to cutting-edge radii and surface roughness as well as coating adhesion. The maximum tool life of the tools was then determined in a machining test.

An evaluation of the results shows the direct influence of the individual processes in the respective chain:

  • All cleaning chains without plasma fine-cleaning exhibited a significantly lower coating adhesion and service life than batches with integrated plasma fine-cleaning.
  • The optimized aqueous cleaning has no further influence in the chain, but as an individual process it is at least as good as the reference.
  • CO2-blasting has the technological advantage of a strongly locally fo-cused cleaning possibility.
  • With PEP, in addition to the removal of heavy contamination, cutting-edge radii can also be adjusted.
  • The combination of PEP with CO2-blasting exhibits the highest overall relevance with regard to industrial usability. The sequence thereby se-lected shows no significant influence.

This article is part of the annual report 2019.


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